Royale Union Saint-Gilloise came away with an impressive 1–3 win against PSV in Matchday 1 of the UEFA Champions League on Tuesday, 16 September 2025. The visitors proved too strong, taking the points back on the road.

Union SG held a 0–2 advantage at the break, demonstrating their quality in the first period. The second half continued to produce goals, ending 1–3 at full time.

It was a high-scoring affair with 4 goals in total, providing plenty of entertainment for spectators as PSV and Union SG produced an open and attacking game.

This fixture was part of the UEFA Champions League season. Follow GoalRadar for live scores, results, and full coverage of UEFA Champions League matches throughout the season.